Volume alignment, commonly referred to as sector alignment, should be performed on the file system (NTFS) whenever a volume is created on a RAID device. Failure to do so can lead to significant performance degradation; these are most commonly the result of partition misalignment with stripe unit boundaries. This can also lead to hardware cache misalignment, resulting in inefficient utilization of the array cache. For more information on this, see Disk performance may be slower than expected when you use multiple disks in Windows Server 2003, in Windows XP, and in Windows 2000.
Amit's blog : Disk Partitioning Offset
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